Features of electrochemical processes at the boundary p-GaAs-HF water solution

Investigated in this work are polarization curves typical for the interface p-GaAs-HF water solution with the concentration of fluoric acid between 1 and 10 mass.%. The shape of these curves has been compared with that following from analytical expressions obtained with account of the general equati...

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Published in:Semiconductor Physics Quantum Electronics & Optoelectronics
Date:2018
Main Authors: Pashchenko, G.A., Kravetskyi, M.Yu., Trishchuk, L.I.
Format: Article
Language:English
Published: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2018
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/215287
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Features of electrochemical processes at the boundary p-GaAs-HF water solution / G.A. Pashchenko, M.Yu. Kravetskyi, L.I. Trishchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. —  2018. — Т. 21, № 3. — С. 277-281. — Бібліогр.: 11 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Pashchenko, G.A.
Kravetskyi, M.Yu.
Trishchuk, L.I.
author_facet Pashchenko, G.A.
Kravetskyi, M.Yu.
Trishchuk, L.I.
citation_txt Features of electrochemical processes at the boundary p-GaAs-HF water solution / G.A. Pashchenko, M.Yu. Kravetskyi, L.I. Trishchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. —  2018. — Т. 21, № 3. — С. 277-281. — Бібліогр.: 11 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description Investigated in this work are polarization curves typical for the interface p-GaAs-HF water solution with the concentration of fluoric acid between 1 and 10 mass.%. The shape of these curves has been compared with that following from analytical expressions obtained with account of the general equation for electrochemical kinetics. This equation was considered for partial cases of electrode potential re-distribution between the Helmholtz layers and the space charge region (SCR) in a semiconductor. It has been found that the shape of polarization curves corresponds to the state when exchange reactions at the above boundary for the used HF concentrations take place mainly via the valence band with participation of holes, while the electrode potential redistributes between the semiconductor SCR and the Helmholtz layer. Determined also have been the ranges of current density where transfer of current carriers takes place through the boundary p-GaAs-HF water solution (electrochemical stage), exchange currents for cathode and anode biases, coefficient of charge carrier transfer under the cathode bias.
first_indexed 2026-03-21T12:46:38Z
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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language English
last_indexed 2026-04-16T04:40:41Z
publishDate 2018
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Pashchenko, G.A.
Kravetskyi, M.Yu.
Trishchuk, L.I.
2026-03-11T10:14:58Z
2018
Features of electrochemical processes at the boundary p-GaAs-HF water solution / G.A. Pashchenko, M.Yu. Kravetskyi, L.I. Trishchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. —  2018. — Т. 21, № 3. — С. 277-281. — Бібліогр.: 11 назв. — англ.
1560-8034
PACS: 81.05.Ea, 82.45.Vp
https://nasplib.isofts.kiev.ua/handle/123456789/215287
https://doi.org/10.15407/spqeo21.03.277
Investigated in this work are polarization curves typical for the interface p-GaAs-HF water solution with the concentration of fluoric acid between 1 and 10 mass.%. The shape of these curves has been compared with that following from analytical expressions obtained with account of the general equation for electrochemical kinetics. This equation was considered for partial cases of electrode potential re-distribution between the Helmholtz layers and the space charge region (SCR) in a semiconductor. It has been found that the shape of polarization curves corresponds to the state when exchange reactions at the above boundary for the used HF concentrations take place mainly via the valence band with participation of holes, while the electrode potential redistributes between the semiconductor SCR and the Helmholtz layer. Determined also have been the ranges of current density where transfer of current carriers takes place through the boundary p-GaAs-HF water solution (electrochemical stage), exchange currents for cathode and anode biases, coefficient of charge carrier transfer under the cathode bias.
The authors are very thankful to Candidate of Sciences (Phys&Math) G. V. Beketov for useful consultations.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Semiconductor Physics
Features of electrochemical processes at the boundary p-GaAs-HF water solution
Article
published earlier
spellingShingle Features of electrochemical processes at the boundary p-GaAs-HF water solution
Pashchenko, G.A.
Kravetskyi, M.Yu.
Trishchuk, L.I.
Semiconductor Physics
title Features of electrochemical processes at the boundary p-GaAs-HF water solution
title_full Features of electrochemical processes at the boundary p-GaAs-HF water solution
title_fullStr Features of electrochemical processes at the boundary p-GaAs-HF water solution
title_full_unstemmed Features of electrochemical processes at the boundary p-GaAs-HF water solution
title_short Features of electrochemical processes at the boundary p-GaAs-HF water solution
title_sort features of electrochemical processes at the boundary p-gaas-hf water solution
topic Semiconductor Physics
topic_facet Semiconductor Physics
url https://nasplib.isofts.kiev.ua/handle/123456789/215287
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AT kravetskyimyu featuresofelectrochemicalprocessesattheboundarypgaashfwatersolution
AT trishchukli featuresofelectrochemicalprocessesattheboundarypgaashfwatersolution