Синтез похідних імідазоліну – активної основи антикорозійних засобів

Synthesis of the active base of a solid corrosion inhibitor for the protection of underground equipment of gas condensate and oil wells, namely, 1-amido-hydroxystearate-diethylenediamine-2-hydroxystearyl-imidazoline and ethylene-bis-2-hydroxystearyl-imidazoline is described. Imidazoline derivatives...

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Bibliographische Detailangaben
Datum:2024
Hauptverfasser: Kartun, Igor M., Kochirko, Bogdan F.
Format: Artikel
Sprache:Ukrainisch
Veröffentlicht: V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 2024
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Online Zugang:https://kataliz.org.ua/index.php/journal/article/view/114
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Назва журналу:Catalysis and petrochemistry

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Catalysis and petrochemistry
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Zusammenfassung:Synthesis of the active base of a solid corrosion inhibitor for the protection of underground equipment of gas condensate and oil wells, namely, 1-amido-hydroxystearate-diethylenediamine-2-hydroxystearyl-imidazoline and ethylene-bis-2-hydroxystearyl-imidazoline is described. Imidazoline derivatives have been obtained by condensation of triethyltetramine with 12-hydroxystearic acid at different temperatures. Analysis of the reaction products by 1H NMR spectroscopy and chromatography-mass spectrometry is presented, with confirmation of the formation of target products at each stage of synthesis. It was found that when the reaction is carried out at 280 ℃, a significant amount of ethylene-bis-2-hydroxystearyl-imidazoline is formed. The perspective of using a technical mixture of 1-amido-hydroxystearate-diethylenediamine-2-hydroxystearyl-imidazoline and ethylene-bis-2-hydroxystearyl-imidazoline for anti-corrosion protection of oil pipelines is demonstrated.