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V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine
2026
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ISSN 2707-5769 (Online) ISSN 2412-4176 (Print) Catalysis and Petrochemistry
AUTHOR GUIDELINES
The Collection publishes materials covering pressing issues of catalysis, development of new catalysts
and technological processes, analysis of fundamental and applied aspects of modern petrochemistry,
achievements of basic organic synthesis based on fossil and renewable raw materials.
"Catalysis and Petrochemistry" accepts for consideration review and original scientific articles that
summarize experimental and theoretical research; information on conferences and seminars; short reports that
correspond to the topics of the collection and are aimed at the development of the domestic chemical
industry.
Articles in English and Ukrainian are accepted for publication in the collection.
The collection does not require payment from the author(s) for reviewing manuscripts and publishing
articles. All published materials can be viewed and copied online free of charge on the publication's website
(https://kataliz.org.ua).
All articles submitted to the editorial office are subject to review. Reviewing is conducted
confidentially.
Manuscript submission
The manuscript should be sent to the editorial office's email address catpet20@ukr.net in *.docx format:
- an article in the form of 1 file, which includes the full text of the manuscript with all figures, tables,
a list of references and abstracts. The article must be formatted in accordance with the rules below.
- information about the authors (the form could be downloaded on the website
https://kataliz.org.ua/index.php/j ournal/rules).
Adress: V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry (IBOPC) of the National
Academy of Sciences of Ukraine. Ukraine, 02160, Kyiv-160, Kharkivske shosse, 50.
Writing and formatting
The text is printed in Microsoft Word format using Times New Roman font with 1.0 spacing.
Page orientation is portrait. Page numbering is from the bottom right, starting with the first page.
Manuscript sections (an example of design is given below):
• UDC index for Ukrainian authors (as for 2013) or PACS (in last edition ‘Physics and Astronomy
Classification Scheme 2010’— http://publishing.aip.org/publishing/pacs/pacs-2010-regular-edition);
• Manuscript title (Times New Roman 14, bold);
• Initials and surname(s) of the author(s) (Times New Roman 11, bold);
• Affiliation, post address, author (s) e-mail address (Times New Roman 10, Italics);
• Abstract from 1800 up to 2000 characters (Times New Roman 11, Italics). The abstract should reflect
the main purpose of the study and summarize the most significant results without references to other
publications. Abbreviations, symbols, and mathematical formulas must be omitted in the abstract. Ukrainian
authors should submit the Abstract in Ukrainian and English.
• Key words (Times New Roman 11);
• Manuscript text (Timel New Roman 11), which includes:
Introduction, which outlines the problem statement, the relevance of the chosen topic, an analysis of
recent research and publications, the purpose and objectives of the work.
Experimental, where the starting reagents and experimental procedures are described.
Results and Discussion
Drawings, graphs, and figures are made in the graphic editor Microsoft Excel, Origin, or Photoshop and
are provided in an editable format. Figures are printed in a size no larger than 160^200 mm in the text of the
article. The quality of illustrations should ensure their reproduction with a resolution of 300-600 dpi. The text
in the figures should be replaced as much as possible with numbers or letters, which are deciphered in the
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to the figure. In graphs, units of measurement are indicated through a dot.
Formulas m ust be typed in the formula editors MatType, ChemDraw, ISIS/Draw or Microsoft Equation.
Articles with formulas written by hand will not be accepted for publication. Symbols such as sin, max, exp, log,
lim, 0 (zero), and names of chemical elements must be typed straight, not in Italics.
Tables should be formatted using the MS Word spreadsheet editor (10 pt) and presented in the text after the first
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reference to the table, indicating its number and title. Tables should have a title, each column of the
table - a subtitle that defines the content of the column. Column headings should be written completely in bold, without
abbreviations, indicating units of measurement. Only variable values should be placed in tables, constant experimental conditions
are given in the text or table title in brackets. Notes to the table are printed immediately after it. If the manuscript contains one
table, then it is not numbered.
Conclusions, where the results of the work and prospects for further research in this direction are summarized.
Acknowledgements for assistance with work or financial support (optinal).
References. It is advisable to include references with active digital DOI identifiers in the list of references, as well as
those indexed in leading international scientometric databases (Scopus, Web of Science, etc.). References to materials and
proceedings of international conferences (except for those indexed in international scientometric databases), abstracts of
dissertations and theses, patents, electronic resources (Internet sites, etc.) can be used only as an exception.
It is prohibited to refer to unpublished works, as well as to materials and abstracts of regional conferences, textbooks,
teaching aids, methodological guidelines, regulatory legal acts, standards, etc. In case of extreme necessity, such a reference can
be made in the form of a footnote or inline reference.
Preference should be given to references published after 2010, and especially after 2020. Older references should not
make up more than 1/3 of the list. The list of references may include no more than 10% of references to works published earlier
in "Catalysis and Petrochemistry". Self-citations should not exceed 25% for experimental works and 30% for review papers.
Rules for English and Ukrainian references are given below.
Abstract in English (if the manuscript wrote in Ukrainian) or in Ukrainian (for Ukrainian authors if the manuscript is in
English) should be given on separate sheet of paper and must include:
• Manuscript title (Times New Roman 14, bold),
• Initials and surname(s) of the author(s) (Times New Roman 11, bold),
• Affiliation, post address, author (s) e-mail address (Times New Roman 10, Italics),
• Abstract from 1800 up to 2000 characters (Times New Roman 11, Italics).
• Key words (Times New Roman 11);
For article in English, References are formatted as follows:
1. Nanda S., Golemi-Kotra D., McDermott J.C., Dalai A.K., Gokalp I., Kozinski J.A. Fermentative production of butanol:
Perspectives on synthetic biology. New Biotechnol., 2017, 37, 210-221.
2. Uyttebroek M., Van Hecke W., Vanbroekhoven K. Sustainability metrics of 1-butanol. Catal. Today, 2015, 239, 7-10.
3. Zheng J., Tashiro Y., Wang Q., Sonomoto K. Recent advances to improve fermentative butanol production: Genetic
engineering and fermentation technology. J. Biosci. Bioeng., 2015, 119, 1-9.
4. Gabriels D., Hernandez W. Y., Sels B., Van Der Voort P., Verberckmoes A. Review of catalytic systems and thermodynamics
for the Guerbet condensation reaction and challenges for biomass valorization. Catal. Sci. Technol., 2015, 5, 3876-
3902.
5. Patent US 8779216 B2. Wick A. and Mahnke E.U. Method for producing guerbet alcohols. 2014.
6. Patent US 20130068457 A1. Thach S., Shong R., Dwarakanath V., Winslow G. Method of manufacture of guerbet alcohols
for making surfactants used in petroleum industry operations. 2013.
7. Patent WO 2013120757 AI. Thach S., Shong R., Dwarakanath V., Winslow G. Alcools de guerbet en tant que substituts de
la Vaseline. 2013.
8. http ://www.iza-structure.org/databases/
9. Khalameida S. et al. Effect of mechanochemical modification on properties of powder tin(IV) oxide and oxohydroxide.
Chemistry, Physics and Technology of Surface, 2017, 8(3), 271-288. [in Ukranian].
10. Wu T. et al. Photoassisted degradation of dye pollutants. V. Self-photosensitized oxidative transformation of Rhodamine B
under visible light irradiation in aqueous TiO2 dispersions. J. Phys. Chem. B, 1998, 102(30), 5845-5851.
The list of used literary sources for an article in Ukrainian should consist of two parts: Literature, where references are
provided in the language of the original publication and References (language of transliteration). References are provided
without DOI. Examples:
Література
http://www.iza-structure.org/databases/
1. Брей В.В., Щуцький І.В., Підсадюк І.М. Нова вітчизняна HPPOa технологія виробництва пропіленоксиду. Вісник
НАН України, 2022, 1, 63-68.
2. Brazhnyk D.V., Zaitsev Yu.P., Bacherikova I.V., Zazhigalov V.A., Stoch J., Kowal A. Oxidation of H2S on activated carbon
KAU and influence of the surface state. Appl. Catal. B., 2007, 70(1-4), 557-566.
3. Діюк О.А., Зажигалов В.О. Спосіб одержання нанесеного ванадій-фосфорного оксидного (VPO) каталізатора
окиснення н-бутану в малеїновий ангідрид. Пат. 121051 Україна, Патент на корисну модель (власник
Інститут сорбції та проблем ендоекології НАН України). Опубл. 27.11.2017р., бюл. № 22.
References
1. Brei V.V., Shchutskyi I.V., Pidsadyuk I.M. New domestic HPPOa technology for propylene oxide production .Visnyk of
the National Academy of Sciences of Ukraine, 2022, 1,63-68 [in Ukrainian].
2. Brazhnyk D.V., Zaitsev Yu.P., Bacherikova I.V., Zazhigalov V.A., Stoch J., Kowal A. Oxidation of H2S on activated carbon
KAU and influence of the surface state. Appl. Catal. B., 2007, 70(1-4), 557-566.
3. Diyuk O.A., Zazhigalov V.O. Sposib oderzhannya nanesenogo vanadii-fosfornogo oksidnogo (VPO) katalizatora okisleniya
n-butana v maleinovyi anhydride. Pat. 121051 Ukraina, Patent na kotysnu model’. Vlasnyk Instytut sorbcii to problem
endoekologii NAN Ukrainy. Opubl. 27.11.2017, bul. N 22. [in Ukrainian].
None of the examples listed use punctuation marks: //, - (em dash), “...”.
Example of the manuscript in English UDC544.473
https://doi.org/10.15407/kataliz2023.34.050
Vapour phase Guerbet condensation of ethanol to 1-butanol on CsX zeolite
Lyubov K. Patrylak 1 2, Olexandra P. Pertko 1, Karina V. Valihura 3 4 Yulia G. Voloshyna 1
1 V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of
Ukraine 50 Kharkivske shose, Kyiv, 02160, Ukraine, e-mail: lkpg@ukr.net
2 National Technical University of Ukraine “Igor Sikorskyi Kyiv Polytechnic Institute "
37/4 Beresteiskyi Avenue, Kyiv, 03056, Ukraine
3 L. V. Pisarzhevskii Institute of Physical Chemistry of National Academy of Sciences of
Ukraine 31 Nauky Avenue, Kyiv, 03028, Ukraine
4 Department of Chemical and Environmental Engineering, Higher Technical School of
Engineering University of Seville, Camino de los Descubrimientos w/n, 41092 Seville, Spain
Nowadays, the conversion of ethanol into valuable chemical products is getting wider application. One of such
promising processes is Guerbet condensation of alcohols, which permits the obtaining of 1-butanol from renewable raw
materials that are alternatives to petroleum ones. Oxide systems combining acid and basic sites in their composition are
promising catalysts for such a transformation. In this study, the efficiency of the magnesium-aluminum oxide and zirconium-
oxide catalysts was compared to the activity of the cesium form of X-type zeolite produced by hydrothermal ion exchange in
the condensation of ethanol to 1-butanol. The integrity of the zeolite structure was confirmed by using the XRD and XRF
analysis, as well as by the IR spectroscopy. The depth of exchange of native sodium for cesium was 82 %. It was also found
that cesium cations are localized only in ion-exchange positions of faujasite, in places SIII (supercages) and SI' (sodalite cages).
CsX zeolite acid to basic sites ratio was found to be close to optimal for this reaction. Cesium-containing zeolite at 300 °C
shows ethanol 35-55 % conversion and 20-25 % selectivity for 1-butanol, which is higher than the same characteristics for
zirconium samples, but slightly inferior to magnesium-aluminum oxide catalysts. The obtained results indicate the promising
use of zeolites of a similar nature in the process of condensation of ethanol to 1-butanol.
Keywords: ethanol condensation, 1-butanol, acid sites, basic sites, 1-butanol yield, process selectivity
mailto:lkpg@ukr.net
https://doi.org/10.15407/kataliz2023.34.050
Introduction
1-Butanol is widely used as a solvent, extractant, and raw material for the production of methacrylates and butyl acrylate
for coatings, enamels, and varnishes [1, 2]. A relatively new field of application for 1- butanol is its addition to gasoline instead
of ethanol [2-5]. ...
Experimental
Catalyst synthesis
X-type zeolite (SiO2/Al2O3 = 2.3, TU 38.102168-85, static capacity for water vapor: 0.30 cm3/g, for benzene vapor: 0.29
cm 3/g, fraction 0.5-1 mm) was subjected to a two-time exchange for cesium cations from a 1 N aqueous solution of nitrate
(chemically pure, TU 6-09-437-83) for cesium form synthesis. ...
Results and Discussion
Catalyst characterization
Based on the X-ray fluorescence analysis data, the SiO2 to AhO3 ratio in the zeolite framework and the degree of cesium
exchange were calculated to be 2.5 and 82 %, respectively. Therefore, during the ion exchange procedure, the chemical
composition of the aluminosilicate framework of the zeolite undergoes only minor changes .
Fig. 1. 133Cs (a), 23Na (b), and 27Al (c) NMR spectra for CsX sample
Table 1. Charaterictics of porous structure of zeolite samples according to low temperature nitrogen
Sample SBET,
m2/g
S
miсro
,
m2/g
V ■
micro
cm3/g
V,
cm3/g
V micro/V£ R,
nm
NaX 689 669 0.279 0.323 0.86 0.9
CsX 345 329 0.140 0.180 0.79 1.0
Conclusions
According to the results of X-ray diffraction and X-ray fluorescence analysis, NMR, and IR spectral studies, the CsX
zeolite synthesized by ion exchange with a high degree of sodium to cesium exchange retained its crystalline structure. In
particular, in the 133 Cs NMR spectrum of zeolite, there are two signals of chemical shifts, -116 and -160 ppm, reflecting
cesium cations in supercages and sodalite cages (sites SIII and SI', respectively). ...
Acknowledgments
The authors express their gratitude to the senior researcher, candidate of chemical sciences O.I. Oranska and leading
engineer Yu.I. Gornikov (O.O. Chuiko Institute of Surface Chemistry, NAS of Ukraine)
for conducting an X-ray diffraction analysis of the samples, and the senior researcher, candidate of chemical sciences V.V.
Trachevskyi (Technical center of National Academy of Sciences of Ukraine) for NMR measurements.
References
1. Ndaba B., Chiyanzu I., Marx S. n-Butanol derived from biochemical and chemical routes: A review. Biotechnol. Reports,
2015, 8, 1-9.
2. Rajesh Kumar B., Saravanan S. Use of higher alcohol biofuels in diesel engines: A review. Renew. Sustain.
Energy Rev., 2016, 60, 84-115.
3. Roberto W., Trindade S., Gonsalves R., Santos D. Review on the characteristics of butanol, its production and use as fuel in
internal combustion engines. Renew. Sustain. Energy Rev., 2016, 69, 642-651.
Парофазна конденсація етанолу до 1-бутанолу за Гербе на цеоліті СзХ
Любов К. Патриляк 1 2, Олександра П. Пертко 1, Каріна В. Валігура 3’ 4, Юлія Г. Волошина 1
1 Інститут біоорганічної хімії та нафтохімії ім. В.П. Кухаря Національної академії наук
України Харківське шосе, 50, Київ, 02160, Україна, lkpg @ ukr . net
2 Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського»
Берестейський просп., 37/4, Київ, 03056, Україна
3 Інститут фізичної хімії імені Л.В. Писаржевського Національної академії наук
України просп. Науки, 31, Київ, 03028, Україна
4 Відділ хімічної та екологічної інженерії, Вища технічна школа
інженерії Університет Севільї, 41092, Севілья, Іспанія
Перетворення етанолу у цінні хімічні продукти набуває все ширшого застосування. Одним із таких
перспективних процесів є конденсація спиртів за Гербе, що дозволяє отримувати 1-бутанол із альтернативної нафтовій
відновлювальної сировини. Багатообіцяючими каталізаторами такого перетворення є оксидні системи, що поєднують
у своєму складі кислотні та основні центри. У даній роботі оцінено активність у конденсації етанолу до 1-бутанолу
цезієвої форми цеоліту типу Х, одержаної гідротермальним іонним обміном, а також проведено порівняння її
ефективності з магній-алюміній- оксидними та цирконій-оксидними каталізаторами. Цілісність цеолітної структури
підтверджено методами рентгенофазового та рентгенофлуорисцентного аналізу, а також ІЧ-спектроскопії. Ступінь
обміну натрію на цезій склав 82 %. Знайдено також, що катіони цезію локалізовані лише у іонообмінних позиціях
фожазиту - в місцях SШ (великі порожнини) та SI' (содалітові комірки). Встановлено, що цеоліт CsX має близькі до
оптимального для даного перетворення співвідношення між кількістю кислотних та основних центрів. Цезійвмісний
цеоліт за 350 °С демонструє 35-55 % конверсію етанолу та 20-25 % селективність за 1-бутанолом, що є вищим за
показники для цирконієвих зразків, але дещо поступається магній-алюмінієвим каталізаторам. Одержані результати
свідчать про перспективність використання цеолітів близької природи у процесі конденсації етанолу до 1-бутанолу.
Ключові слова: конденсація етанолу, 1-бутанол, кислотні центри, основні центри, вихід 1-бутанолу,
селективність процесу
mailto:lkpg@ukr.net
None of the examples listed use punctuation marks: //, - (em dash), “...”.
Example of the manuscript in English UDC544.473
Vapour phase Guerbet condensation of ethanol to 1-butanol on CsX zeolite
Lyubov K. Patrylak 1 2, Olexandra P. Pertko 1, Karina V. Valihura 3 4 Yulia G. Voloshyna 1
References
Парофазна конденсація етанолу до 1-бутанолу за Гербе на цеоліті СзХ
Любов К. Патриляк 1 2, Олександра П. Пертко 1, Каріна В. Валігура 3’ 4, Юлія Г. Волошина 1
|
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| institution | Catalysis and petrochemistry |
| keywords_txt_mv | keywords |
| language | English |
| last_indexed | 2026-03-12T15:50:26Z |
| publishDate | 2026 |
| publisher | V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine |
| record_format | ojs |
| resource_txt_mv | katalizorgua/c7/5981391ca999abf496c23bae7305d2c7.pdf |
| spelling | oai:katalizorgua:article-1472026-03-11T15:06:53Z Author rules Правила для авторів katalizadmin, katalizadmin Author rules Правила для авторів V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 2026-03-11 Article Article application/pdf https://kataliz.org.ua/index.php/journal/article/view/147 Catalysis and petrochemistry; No. 27 (2018): Catalysis and petrochemistry; 85 Каталіз та нафтохімія; № 27 (2018): Каталіз та нафтохімія; 85 2707-5796 2412-4176 en https://kataliz.org.ua/index.php/journal/article/view/147/123 |
| spellingShingle | katalizadmin, katalizadmin Правила для авторів |
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| title_full_unstemmed | Правила для авторів |
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| url | https://kataliz.org.ua/index.php/journal/article/view/147 |
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