Новий зручний спосіб отримання тетрабутиламоній клозо-додекаборату

• Published in: Журнал органічної та фармацевтичної хімії
• Date: 2025
• Volume: 22
• Issue: 4
• Pages: 3-9
• ISSN: 2518-1548
• Author Affiliations: Artem M. Mishchenko — Enamine Ltd.; Maxim A. Nechayev — Enamine Ltd.; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Andrii I. Subota — Enamine Ltd.; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Andriy V. Kozytskiy — Enamine Ltd.; Oleh V. Svaliavyn — Enamine Ltd.; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Yulian L. Lishchenko — Enamine Ltd.; L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine; Anastasiia M. Aleksandrova — Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Yuliya V. Rassukana — Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Dmytro O. Leha — Taras Shevchenko National University of Kyiv; Enamine Ltd. — ORCID: 0000-0002-4505-3646
• Main Authors: Mishchenko, Artem M., Nechayev, Maxim A., Subota, Andrii I., Kozytskiy, Andriy V., Svaliavyn, Oleh V., Lishchenko, Yulian L., Aleksandrova, Anastasiia M., Rassukana, Yuliya V., Leha, Dmytro O.
• Format: Article
• Language: English
• Published: National University of Pharmacy 2025
• Subjects: клозо-додекаборат; октагідротриборат; піроліз; DFT-розрахунки
• Online Access: https://ophcj.nuph.edu.ua/article/view/316264
• Journal Title: Journal of Organic and Pharmaceutical Chemistry

A new synthetic procedure for preparing tetrabutylammonium closo-dodecaborate (Bu4N)2B12H12 by the solvent-free pyrolysis of tetrabutylammonium tetrahydroborate Bu4NBH4 has been developed. The procedure also provides isolation of pure tetrabutylammonium octahydrotriborate Bu4NB3H8 as a by-product. T...