Оптимізація та масштабування методу синтезу похідних азаіндолу

In this study, an optimized method for the synthesis of azaindoles was developed and successfully scaled up to a 100 g batch. Improved yields were observed when using electron-deficient azaheterocycles and substrates bearing electron-withdrawing substituents. 6-Chloro-1H-pyrrolo[3,2-c]pyridine was s...

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Збережено в:
Бібліографічні деталі
Дата:2025
Автори: Kordubailo, Mykyta V., Tolmachev, Andrey A.
Формат: Стаття
Мова:English
Опубліковано: National University of Pharmacy 2025
Теми:
Онлайн доступ:https://ophcj.nuph.edu.ua/article/view/323307
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Назва журналу:Journal of Organic and Pharmaceutical Chemistry

Репозитарії

Journal of Organic and Pharmaceutical Chemistry
Опис
Резюме:In this study, an optimized method for the synthesis of azaindoles was developed and successfully scaled up to a 100 g batch. Improved yields were observed when using electron-deficient azaheterocycles and substrates bearing electron-withdrawing substituents. 6-Chloro-1H-pyrrolo[3,2-c]pyridine was selected for further functionalization using a carbonylation protocol involving carbon monoxide. As a result, novel and promising building blocks for medicinal chemistry were obtained.