Сорбція гетерополікислот на целюлозних сорбентах

Sorption of heteropoly acids on the surfaces of cellulose and diethylaminoethylcellulose with molybdovanadophosphoric acid as an example has been studied by UV-VIS, infrared, and MAS-NMR spectroscopy. It has been shown that sorption of heteropoly acid on diethylaminoethylcellulose is substantially h...

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Збережено в:
Бібліографічні деталі
Дата:2012
Автори: Zui, O. V., Zaitsev, V. N., Alekseev, S. A., Trachevsky, V. V.
Формат: Стаття
Мова:Російська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2012
Онлайн доступ:https://www.cpts.com.ua/index.php/cpts/article/view/147
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Назва журналу:Chemistry, Physics and Technology of Surface

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Chemistry, Physics and Technology of Surface
Опис
Резюме:Sorption of heteropoly acids on the surfaces of cellulose and diethylaminoethylcellulose with molybdovanadophosphoric acid as an example has been studied by UV-VIS, infrared, and MAS-NMR spectroscopy. It has been shown that sorption of heteropoly acid on diethylaminoethylcellulose is substantially higher than that on ordinary cellulose. The mechanism of sorption includes combination of Coulomb and hydrophobic interactions. A scheme of heteropoly acids immobilization has been proposed based on ion exchange on cellulose surface.