Адсорбція хітозану на поверхні змішаних оксидів

The adsorption isotherms of chitosan on silica, silica-titania and silica-alumina have surfaces been obtained. The adsorption capability was found to decrease in the row silica-alumina>silica-titania> silica. Chitosan modified oxides have been examined by the temperature-progra...

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Bibliographic Details
Date:2008
Main Authors: Borodavka, T. V., Palyanytsya, B. B., Kulik, T. V.
Format: Article
Language:Ukrainian
Published: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2008
Online Access:https://surfacezbir.com.ua/index.php/surface/article/view/270
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Journal Title:Surface
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Summary:The adsorption isotherms of chitosan on silica, silica-titania and silica-alumina have surfaces been obtained. The adsorption capability was found to decrease in the row silica-alumina>silica-titania> silica. Chitosan modified oxides have been examined by the temperature-programmed desorption mass spectrometry method. The low-temperature peaks of the thermo-desorption curves of chitosan destruction occur for silica-titania and silica-alumina as well as for individual silica. These low-temperature maxima correspond to the thermolysis of trains of adsorbed polymer. Thermolysis of chitosan on silica-titania and silica-alumina has been shown to realize with deep destruction of pyranosic rings and breaking of  C–C bonds in contrast to thermolysis of chitosan on silica surface.