Matrix synthesis, structural and adsorption properties of porous polymeric materials

A research has been carried out on template polymerization of phenolformaldehide oligomer in of surfactant solutions, as well as on exotemplate synthesis of divinylbenzene in mesoporous SBA-15 type molecular sieve. Influence of template type, mesoporous matrix pore filling degree with an initial mon...

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Bibliographic Details
Date:2008
Main Author: Opanasenko, M. V.
Format: Article
Language:Russian
Published: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2008
Online Access:https://surfacezbir.com.ua/index.php/surface/article/view/298
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Journal Title:Surface
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Summary:A research has been carried out on template polymerization of phenolformaldehide oligomer in of surfactant solutions, as well as on exotemplate synthesis of divinylbenzene in mesoporous SBA-15 type molecular sieve. Influence of template type, mesoporous matrix pore filling degree with an initial monomer, medium, temperature, and time of polymerization, as well as method of silica removal on the structural and sorption properties of porous polymeric materials were investigated. Surplus mesopore filling with monomer, polymerization in vacuum, and alkaline method of exotemplate removal have been demonstrated to be preferable