Спектрофотометричне вивчення взаємодії β-циклодекстрину та бензену у водних розчинах

The interaction of molecules of benzene and β-cyclodextrin in aqueous solutions has been studied by means of UV spectroscopy. Given the change of absorption parameters of UV spectra of aqueous solutions of benzene after adding β-cyclodextrin a stoichiometric composition and...

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Datum:2009
Hauptverfasser: Trofymchuk, I. M., Lyashenko, D. Yu., Belyakova, L. A.
Format: Artikel
Sprache:Ukrainisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2009
Online Zugang:https://surfacezbir.com.ua/index.php/surface/article/view/331
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Назва журналу:Surface
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Zusammenfassung:The interaction of molecules of benzene and β-cyclodextrin in aqueous solutions has been studied by means of UV spectroscopy. Given the change of absorption parameters of UV spectra of aqueous solutions of benzene after adding β-cyclodextrin a stoichiometric composition and formation parameters of supramolecular structures “β-cyclodextrin –benzene” were established. It was proved, that in aqueous solutions essentially 1:1 inclusion complex [β-CD] : [Benz] is formed. Stability constant for 1:1 inclusion complex at 18 – 30 °С, and thermodynamic parameters of its formation were calculated.