Багатограмовий синтез β-флуорованих насичених гетероциклічних метанамінів

An efficient multigram synthesis of β-fluorinated saturated heterocyclic methanamines - promising building blocks for drug discovery, starting from the corresponding saturated heterocyclic ketones is described. The method includes Wittig olefination, bromofluorination, nucleophilic substitution with...

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Datum:2023
Hauptverfasser: Semeno, Volodymyr V., Melnykov, Kostiantyn P.
Format: Artikel
Sprache:English
Veröffentlicht: V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 2023
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Online Zugang:https://bioorganica.com.ua/index.php/journal/article/view/73
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Назва журналу:Ukrainica Bioorganica Acta

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Ukrainica Bioorganica Acta
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Zusammenfassung:An efficient multigram synthesis of β-fluorinated saturated heterocyclic methanamines - promising building blocks for drug discovery, starting from the corresponding saturated heterocyclic ketones is described. The method includes Wittig olefination, bromofluorination, nucleophilic substitution with azide, and Staudinger reaction and works well for four- to seven-membered nitrogen- and oxygen-containing heterocyclic derivatives