Особливості процесів корозії в системі протектор на основі алюмінію–сталі
Physico-Techological institure of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine) UDK 669.2/.8:669.55:620.193 Literary analysis of corrosion properties of tread alloys based on zinc and aluminum is performed. The influence of some chemical elements on the properties of treads with high alumi...
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протектор сплави на основі алюмінію корозія добавка кальцій залізо |
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протектор сплави на основі алюмінію корозія добавка кальцій залізо Верховлюк, А. М. Каніболоцький, Д. С. Науменко, М. І. Щерецький, О. А. Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| topic_facet |
протектор сплави на основі алюмінію корозія добавка кальцій залізо protector aluminum-based alloys corrosion additive calcium iron |
| format |
Article |
| author |
Верховлюк, А. М. Каніболоцький, Д. С. Науменко, М. І. Щерецький, О. А. |
| author_facet |
Верховлюк, А. М. Каніболоцький, Д. С. Науменко, М. І. Щерецький, О. А. |
| author_sort |
Верховлюк, А. М. |
| title |
Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_short |
Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_full |
Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_fullStr |
Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_full_unstemmed |
Особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_sort |
особливості процесів корозії в системі протектор на основі алюмінію–сталі |
| title_alt |
Features of Corrosion Processes in the Aluminum-Steel Protector System |
| description |
Physico-Techological institure of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine)
UDK 669.2/.8:669.55:620.193
Literary analysis of corrosion properties of tread alloys based on zinc and aluminum is performed. The influence of some chemical elements on the properties of treads with high aluminum content is analyzed. The method of obtaining alloy samples for corrosion research has been improved. Corrosion tests of steel and steel together with aluminumbased treads containing calcium and iron in model seawater were carried out. The samples were in contact with aggressive environments for 240 hours. It has been established that steel without treads corrodes an order of magnitude more than steel that is not protected by treads. Corrosion of steel with tread does not depend on whether the tread is used with the addition of iron or calcium: the data for these two cases coincide within the experimental errors. But calcium protectors themselves lose weight faster than iron protectors. Thus, it is shown that calcium hyperactivates the tread alloy and reduces its capacity and efficiency.
Keywords: tread, aluminum alloys, corrosion, add
References
1 Rousseau C., Baraud F., Leleyter L., Gil O. (2009). Cathodic protection by zinc sacrificial anodes: Impact on marine sediment metallic contamination. Journal of Hazardous Materials. V. 167. P. 953–958. 2 Crundwell R. F. (2010). Sacrificial Anodes. Shreir's Corrosion, 4th edition. V. 4: Management and control of corrosion. Amsterdam, Boston, Heidelberg [etc.]: Elsevier, 1058 p. P. 2763–2780. 3 Idusuyi N., Oluwole O. O. (2012). Aluminium Anode Activation Research. A Review. International Journal of Science and Technology. V. 2 No. 8. P. 561–566. 4 Sacrificial Anodes. A Longer Life. Ridderkerk, Netherlands: MME Group. 160 p. 5 Sacrificial Anodes. Leerdam, Netherlands: AMPAK® Cathodic Protection. 188 p. 6 Umoru L. E., Ige O. O. (2007). Effects of Tin on Aluminum–Zinc–Magnesium Alloy as Sacrificial Anode in Seawater. Journal of Minerals & Materials Characterization & Engineering. V. 7, No.2. P. 105–113. 7 Rosenfeld I. L. Zhigalova K. A. (1996). Accelerated methods of corrosion testing of metals. M.: Metallurgiya. 348 p. [in Russian]. 8 GOST 6709-72. Distilled water. Specifications. Introduced. 01/01/74. M.: Publishing house of standards, 1973. 23 p. [in Russian]. 9 GOST 24104-88. Scales laboratory of general purpose and exemplary. General specifications. Introduced. 01/01/89. M.: Publishing house of standards, 1988. 30 p. [in Russian].10 GOST 9.908-85. Metals and alloys. Unified system of protection against corrosion and aging. Methods for determining the indicators of corrosion and corrosion resistance. Introduced. 10/31/85. M.: Publishing house of standards, 1985. 18 p. [in Russian].11 Semenova I. V., Florianovich G. M., Khoroshilov A. V. (2002). Corrosion and corrosion protection, Ed. by I. V. Semenova. M.: FIZMATLIT. 336 p. [in Russian].12 Zhuk N. P. (2006). Course of the theory of corrosion and protection of metals. M.: LLC TID "Alliance". 472 p. [in Russian].
Physico-Techological institure of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine)
UDK 669.2/.8:669.55:620.193
Literary analysis of corrosion properties of tread alloys based on zinc and aluminum is performed. The influence of some chemical elements on the properties of treads with high aluminum content is analyzed. The method of obtaining alloy samples for corrosion research has been improved. Corrosion tests of steel and steel together with aluminumbased treads containing calcium and iron in model seawater were carried out. The samples were in contact with aggressive environments for 240 hours. It has been established that steel without treads corrodes an order of magnitude more than steel that is not protected by treads. Corrosion of steel with tread does not depend on whether the tread is used with the addition of iron or calcium: the data for these two cases coincide within the experimental errors. But calcium protectors themselves lose weight faster than iron protectors. Thus, it is shown that calcium hyperactivates the tread alloy and reduces its capacity and efficiency.
References
1 Rousseau C., Baraud F., Leleyter L., Gil O. (2009). Cathodic protection by zinc sacrificial anodes: Impact on marine sediment metallic contamination. Journal of Hazardous Materials. V. 167. P. 953–958. 2 Crundwell R. F. (2010). Sacrificial Anodes. Shreir's Corrosion, 4th edition. V. 4: Management and control of corrosion. Amsterdam, Boston, Heidelberg [etc.]: Elsevier, 1058 p. P. 2763–2780. 3 Idusuyi N., Oluwole O. O. (2012). Aluminium Anode Activation Research. A Review. International Journal of Science and Technology. V. 2 No. 8. P. 561–566. 4 Sacrificial Anodes. A Longer Life. Ridderkerk, Netherlands: MME Group. 160 p. 5 Sacrificial Anodes. Leerdam, Netherlands: AMPAK® Cathodic Protection. 188 p. 6 Umoru L. E., Ige O. O. (2007). Effects of Tin on Aluminum–Zinc–Magnesium Alloy as Sacrificial Anode in Seawater. Journal of Minerals & Materials Characterization & Engineering. V. 7, No.2. P. 105–113. 7 Rosenfeld I. L. Zhigalova K. A. (1996). Accelerated methods of corrosion testing of metals. M.: Metallurgiya. 348 p. [in Russian]. 8 GOST 6709-72. Distilled water. Specifications. Introduced. 01/01/74. M.: Publishing house of standards, 1973. 23 p. [in Russian]. 9 GOST 24104-88. Scales laboratory of general purpose and exemplary. General specifications. Introduced. 01/01/89. M.: Publishing house of standards, 1988. 30 p. [in Russian].10 GOST 9.908-85. Metals and alloys. Unified system of protection against corrosion and aging. Methods for determining the indicators of corrosion and corrosion resistance. Introduced. 10/31/85. M.: Publishing house of standards, 1985. 18 p. [in Russian].11 Semenova I. V., Florianovich G. M., Khoroshilov A. V. (2002). Corrosion and corrosion protection, Ed. by I. V. Semenova. M.: FIZMATLIT. 336 p. [in Russian].12 Zhuk N. P. (2006). Course of the theory of corrosion and protection of metals. M.: LLC TID "Alliance". 472 p. [in Russian]. |
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National Academy of Sciences of Ukraine, Physical-Technological Institute of Metals and Alloys of NAS of Ukraine |
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2023 |
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https://plit-periodical.org.ua/index.php/plit/article/view/features-corrosion-processes-aluminum-steel-protector-system |
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oai:ojs2.localhost:article-172023-05-31T05:04:18Z Features of Corrosion Processes in the Aluminum-Steel Protector System Особливості процесів корозії в системі протектор на основі алюмінію–сталі Верховлюк, А. М. Каніболоцький, Д. С. Науменко, М. І. Щерецький, О. А. протектор сплави на основі алюмінію корозія добавка кальцій залізо protector aluminum-based alloys corrosion additive calcium iron Physico-Techological institure of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine) UDK 669.2/.8:669.55:620.193 Literary analysis of corrosion properties of tread alloys based on zinc and aluminum is performed. The influence of some chemical elements on the properties of treads with high aluminum content is analyzed. The method of obtaining alloy samples for corrosion research has been improved. Corrosion tests of steel and steel together with aluminumbased treads containing calcium and iron in model seawater were carried out. The samples were in contact with aggressive environments for 240 hours. It has been established that steel without treads corrodes an order of magnitude more than steel that is not protected by treads. Corrosion of steel with tread does not depend on whether the tread is used with the addition of iron or calcium: the data for these two cases coincide within the experimental errors. But calcium protectors themselves lose weight faster than iron protectors. Thus, it is shown that calcium hyperactivates the tread alloy and reduces its capacity and efficiency. Keywords: tread, aluminum alloys, corrosion, add References 1 Rousseau C., Baraud F., Leleyter L., Gil O. (2009). Cathodic protection by zinc sacrificial anodes: Impact on marine sediment metallic contamination. Journal of Hazardous Materials. V. 167. P. 953–958. 2 Crundwell R. F. (2010). Sacrificial Anodes. Shreir's Corrosion, 4th edition. V. 4: Management and control of corrosion. Amsterdam, Boston, Heidelberg [etc.]: Elsevier, 1058 p. P. 2763–2780. 3 Idusuyi N., Oluwole O. O. (2012). Aluminium Anode Activation Research. A Review. International Journal of Science and Technology. V. 2 No. 8. P. 561–566. 4 Sacrificial Anodes. A Longer Life. Ridderkerk, Netherlands: MME Group. 160 p. 5 Sacrificial Anodes. Leerdam, Netherlands: AMPAK® Cathodic Protection. 188 p. 6 Umoru L. E., Ige O. O. (2007). Effects of Tin on Aluminum–Zinc–Magnesium Alloy as Sacrificial Anode in Seawater. Journal of Minerals & Materials Characterization & Engineering. V. 7, No.2. P. 105–113. 7 Rosenfeld I. L. Zhigalova K. A. (1996). Accelerated methods of corrosion testing of metals. M.: Metallurgiya. 348 p. [in Russian]. 8 GOST 6709-72. Distilled water. Specifications. Introduced. 01/01/74. M.: Publishing house of standards, 1973. 23 p. [in Russian]. 9 GOST 24104-88. Scales laboratory of general purpose and exemplary. General specifications. Introduced. 01/01/89. M.: Publishing house of standards, 1988. 30 p. [in Russian].10 GOST 9.908-85. Metals and alloys. Unified system of protection against corrosion and aging. Methods for determining the indicators of corrosion and corrosion resistance. Introduced. 10/31/85. M.: Publishing house of standards, 1985. 18 p. [in Russian].11 Semenova I. V., Florianovich G. M., Khoroshilov A. V. (2002). Corrosion and corrosion protection, Ed. by I. V. Semenova. M.: FIZMATLIT. 336 p. [in Russian].12 Zhuk N. P. (2006). Course of the theory of corrosion and protection of metals. M.: LLC TID "Alliance". 472 p. [in Russian]. Physico-Techological institure of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine) UDK 669.2/.8:669.55:620.193 Literary analysis of corrosion properties of tread alloys based on zinc and aluminum is performed. The influence of some chemical elements on the properties of treads with high aluminum content is analyzed. The method of obtaining alloy samples for corrosion research has been improved. Corrosion tests of steel and steel together with aluminumbased treads containing calcium and iron in model seawater were carried out. The samples were in contact with aggressive environments for 240 hours. It has been established that steel without treads corrodes an order of magnitude more than steel that is not protected by treads. Corrosion of steel with tread does not depend on whether the tread is used with the addition of iron or calcium: the data for these two cases coincide within the experimental errors. But calcium protectors themselves lose weight faster than iron protectors. Thus, it is shown that calcium hyperactivates the tread alloy and reduces its capacity and efficiency. References 1 Rousseau C., Baraud F., Leleyter L., Gil O. (2009). Cathodic protection by zinc sacrificial anodes: Impact on marine sediment metallic contamination. Journal of Hazardous Materials. V. 167. P. 953–958. 2 Crundwell R. F. (2010). Sacrificial Anodes. Shreir's Corrosion, 4th edition. V. 4: Management and control of corrosion. Amsterdam, Boston, Heidelberg [etc.]: Elsevier, 1058 p. P. 2763–2780. 3 Idusuyi N., Oluwole O. O. (2012). Aluminium Anode Activation Research. A Review. International Journal of Science and Technology. V. 2 No. 8. P. 561–566. 4 Sacrificial Anodes. A Longer Life. Ridderkerk, Netherlands: MME Group. 160 p. 5 Sacrificial Anodes. Leerdam, Netherlands: AMPAK® Cathodic Protection. 188 p. 6 Umoru L. E., Ige O. O. (2007). Effects of Tin on Aluminum–Zinc–Magnesium Alloy as Sacrificial Anode in Seawater. Journal of Minerals & Materials Characterization & Engineering. V. 7, No.2. P. 105–113. 7 Rosenfeld I. L. Zhigalova K. A. (1996). Accelerated methods of corrosion testing of metals. M.: Metallurgiya. 348 p. [in Russian]. 8 GOST 6709-72. Distilled water. Specifications. Introduced. 01/01/74. M.: Publishing house of standards, 1973. 23 p. [in Russian]. 9 GOST 24104-88. Scales laboratory of general purpose and exemplary. General specifications. Introduced. 01/01/89. M.: Publishing house of standards, 1988. 30 p. [in Russian].10 GOST 9.908-85. Metals and alloys. Unified system of protection against corrosion and aging. Methods for determining the indicators of corrosion and corrosion resistance. Introduced. 10/31/85. M.: Publishing house of standards, 1985. 18 p. [in Russian].11 Semenova I. V., Florianovich G. M., Khoroshilov A. V. (2002). Corrosion and corrosion protection, Ed. by I. V. Semenova. M.: FIZMATLIT. 336 p. [in Russian].12 Zhuk N. P. (2006). Course of the theory of corrosion and protection of metals. M.: LLC TID "Alliance". 472 p. [in Russian]. Фізико-технологічний інститут металів та сплавів НАН України (Київ, Україна) УДК 669.2/.8:669.55:620.193 Виконано літературний аналіз корозійних властивостей протекторних сплавів на основі цинку та алюмінію. Проаналізовано вплив деяких хімічних елементів на властивості протекторів з високим вмістом алюмінію. Удосконалено методику одержання зразків сплавів для корозійних досліджень. Проведено корозійні випробування сталі, сталі спільно з протекторами на основі алюмінію, що містять кальцій та залізо в модельній морській воді, зразки контактували з агресивним середовищем 240 год. Встановлено, що сталь без протекторів кородує на порядок сильніше, ніж сталь, яка не захищена протекторами. Корозія сталі з протектором не залежить від того, використаний протектор з додаванням заліза або кальцію: дані для цих двох випадків збігаються в межах експериментальних похибок. Але самі протектори з кальцієм втрачають масу швидше, ніж протектори з залізом. Таким чином, показано, шо кальцій гіперактивує протекторний сплав та зменшує його ємність і коефіцієнт корисної дії. Список літератури 1 Rousseau C., Baraud F., Leleyter L., Gil O. (2009). Cathodic protection by zinc sacrificial anodes: Impact on marine sediment metallic contamination. Journal of Hazardous Materials. V. 167. P. 953–958. 2 Crundwell R. F. (2010). Sacrificial Anodes. Shreir's Corrosion, 4th edition. V. 4: Management and control of corrosion. Amsterdam, Boston, Heidelberg [etc.]: Elsevier, 1058 p. P. 2763–2780. 3 Idusuyi N., Oluwole O. O. (2012). Aluminium Anode Activation Research. A Review. International Journal of Science and Technology. V. 2 No. 8. P. 561–566. 4 Sacrificial Anodes. A Longer Life. Ridderkerk, Netherlands: MME Group. 160 p. 5 Sacrificial Anodes. Leerdam, Netherlands: AMPAK® Cathodic Protection. 188 p. 6 Umoru L. E., Ige O. O. (2007). Effects of Tin on Aluminum–Zinc–Magnesium Alloy as Sacrificial Anode in Seawater. Journal of Minerals & Materials Characterization & Engineering. V. 7, No.2. P. 105–113. 7 Розенфельд И. Л. Жигалова К. А. Ускоренные методы коррозионных испытаний металлов. М.: Металлургия, 1966. 348 с. 8 ГОСТ 6709-72. Вода дистиллированная. Технические условия. Введен. 01.01.74. М.: Изд-во стандартов, 1973. 23 с. 9 ГОСТ 24104-88. Весы лабораторные общего назначения и образцовые. Общие технические условия. Введен. 01.01.89. М.: Изд-во стандартов, 1988. 30 с.10 ГОСТ 9.908-85. Металлы и сплавы. Единая система защиты от коррозии и старения. Методы определения показателей коррозии и коррозионной стойкости. Введен. 31.10.85. М.: Изд-во стандартов, 1985. 18 с.11 Семенова И. В., Флорианович Г. М., Хорошилов А. В. Коррозия и защита от коррозии / Под ред. И.В. Семеновой. М.: ФИЗМАТЛИТ, 2002. 336 с.12 Жук Н.П. Курс теории коррозии и защиты металлов. М.: ООО ТИД «Альянс», 2006. 472 с. National Academy of Sciences of Ukraine, Physical-Technological Institute of Metals and Alloys of NAS of Ukraine 2023-05-28 Article Article application/pdf https://plit-periodical.org.ua/index.php/plit/article/view/features-corrosion-processes-aluminum-steel-protector-system 10.15407/plit2022.02.060 Casting processes; Casting processes №2 (148) 2022 Процеси лиття; Процеси лиття №2 (148) 2022 2707-1626 0235-5884 uk https://plit-periodical.org.ua/index.php/plit/article/view/features-corrosion-processes-aluminum-steel-protector-system/19 Авторське право (c) 2022 А. М. Верховлюк, Д. С. Каніболоцький, М. І. Науменко, О. А. Щерецький https://creativecommons.org/licenses/by-nc-nd/4.0/ |