Microwave Spectroscopy of Torsion Vibrations in Molecules: Approximation of Rigid Constraint on Structural Torsional Parameters ρ and F in Rho Axis Method

• Date: 2012
• Main Author: Ilyushin, V. V.
• Format: Article
• Language: Russian
• Published: Видавничий дім «Академперіодика» 2012
• Online Access: http://rpra-journal.org.ua/index.php/ra/article/view/425
• Journal Title: Radio physics and radio astronomy

In this paper, on example of the molecules with methyl top hindered internal rotation, we consider an approximation of rigid constraint on structural torsional parameters ρ and F in Rho axis method and its applicability to analysis of the observed molecular spectra. In rigid molecular structure appr...