Морфологiчнi характеристики трифторидiв залiза рiзного ступеня гiдратацiї, отриманих гiдротермальним методом

The crystalline and magnetic microstructures and the morphological features of B-FeF3 3H2O, HTB-FeF30.33H2O, and r-FeF3 iron fluorides hydrothermally synthesized and annealed in the argon atmosphere have been studied. The dehydration process of plate-like B-FeF33H2O particles is studied in detail, a...

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Bibliographic Details
Date:2019
Main Authors: Moklyak, V. V., Kotsyubynsky, V. O., Yaremiy, I. P., Kolkovskyy, P. I., Hrubyak, A. B., Zbihley, L. Z.
Format: Article
Language:English
Published: Publishing house "Academperiodika" 2019
Online Access:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2019018
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Journal Title:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Summary:The crystalline and magnetic microstructures and the morphological features of B-FeF3 3H2O, HTB-FeF30.33H2O, and r-FeF3 iron fluorides hydrothermally synthesized and annealed in the argon atmosphere have been studied. The dehydration process of plate-like B-FeF33H2O particles is studied in detail, and the model for corresponding structural modifications is proposed. The developed model is used to synthesize ultradispersed HTB-FeF30.33H2O and r-FeF3 materials. The r-FeF3 phase is found to be partially in the superparamagnetic state, with the particle size being comparable with the average size of coherent scattering regions.