Характерні оптичні властивості плівок нанокомпозитів полісилани/TiO2

Optimal technological conditions for the fabrication of nanocomposite films based on the poly(di-n-hexylsilane) (PDHS) incorporated into a TiO2 nanoporous film have been developed, and such composites are fabricated. Their optical spectra have been investigated in a wide temperature range (15–330) K...

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Datum:2012
Hauptverfasser: Ostapenko, N., Peckus, D., Gulbinas, W., Suto, S., Watanabe, A.
Format: Artikel
Sprache:English
Veröffentlicht: Publishing house "Academperiodika" 2012
Schlagworte:
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Online Zugang:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2021336
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Назва журналу:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Zusammenfassung:Optimal technological conditions for the fabrication of nanocomposite films based on the poly(di-n-hexylsilane) (PDHS) incorporated into a TiO2 nanoporous film have been developed, and such composites are fabricated. Their optical spectra have been investigated in a wide temperature range (15–330) K. It is shown that the distinctive feature of nanocomposite films is related to the predominant fluorescence band of aggregates with respect to the fluorescence bands corresponding to the gauche- and trans-conformations of polymer chains and to the observation of the intense fluorescence band of aggregates even at room temperature.