Характерні оптичні властивості плівок нанокомпозитів полісилани/TiO2

Optimal technological conditions for the fabrication of nanocomposite films based on the poly(di-n-hexylsilane) (PDHS) incorporated into a TiO2 nanoporous film have been developed, and such composites are fabricated. Their optical spectra have been investigated in a wide temperature range (15–330) K...

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Bibliographic Details
Date:2012
Main Authors: Ostapenko, N., Peckus, D., Gulbinas, W., Suto, S., Watanabe, A.
Format: Article
Language:English
Published: Publishing house "Academperiodika" 2012
Subjects:
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Online Access:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2021336
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Journal Title:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Summary:Optimal technological conditions for the fabrication of nanocomposite films based on the poly(di-n-hexylsilane) (PDHS) incorporated into a TiO2 nanoporous film have been developed, and such composites are fabricated. Their optical spectra have been investigated in a wide temperature range (15–330) K. It is shown that the distinctive feature of nanocomposite films is related to the predominant fluorescence band of aggregates with respect to the fluorescence bands corresponding to the gauche- and trans-conformations of polymer chains and to the observation of the intense fluorescence band of aggregates even at room temperature.