Порівняльний аналіз температурної залежності адіабатичних термодинамічних коефіцієнтів для H2O, H2O2, Ar у стані рідини

Temperature dependences of the adiabatic thermodynamic coefficients of water, where the network of hydrogen bonds is formed under certain conditions, have been compared with the corresponding dependences for hydrogen peroxide, where hydrogen bonds do exist, but the network of hydrogen bonds does not...

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Datum:2025
Hauptverfasser: Bulavin, L.A., Zabulonov, Yu.L., Kopcansky, P., Rudnikov, Ye.G.
Format: Artikel
Sprache:English
Ukrainian
Veröffentlicht: Publishing house "Academperiodika" 2025
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Online Zugang:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2023546
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Назва журналу:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Zusammenfassung:Temperature dependences of the adiabatic thermodynamic coefficients of water, where the network of hydrogen bonds is formed under certain conditions, have been compared with the corresponding dependences for hydrogen peroxide, where hydrogen bonds do exist, but the network of hydrogen bonds does not, and for argon with no hydrogen bonds at all. In our opinion, specific temperature dependences of the indicated parameters for water are associated with the existence of a network of hydrogen bonds in water under certain conditions. This network is formed by two dynamic structures (the LWD and HDW phases) and is responsible for the hierarchy of anomalous water properties in a wide temperature interval. In addition, it has been shown that the network of hydrogen bonds substantially affects the behavior of the temperature dependence of the sound propagation speed related to the adiabatic coefficient of liquid compressibility.