Self-purification effect in CdTe:Gd crystals

The temperature dependences (T = 80 – 420 K) of the concentration of charge carriers and the Hall mobility in undoped CdTe and CdTe:Gd single crystals grown by the Bridgman method are studied. It is found that the conductivity type of CdTe:Gd crystals changes with increase in the impurity concent...

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Дата:2008
Автори: Nikonyuk, E.S., Shlyakhovyi, V.L., Kovalets, M.O., Kuchma, M.I., Zakharuk, Z.I., Savchuk, A.I., Yuriychuk, I.M.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2008
Назва видання:Semiconductor Physics Quantum Electronics & Optoelectronics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/118666
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Self-purification effect in CdTe:Gd crystals / E.S. Nikonyuk, V.L.Shlyakhovyi, M.O. Kovalets, M.I. Kuchma, Z.I. Zakharuk, A.I. Savchuk, I.M. Yuriychuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2008. — Т. 11, № 1. — С. 40-42. — Бібліогр.: 7 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1186662017-05-31T03:05:53Z Self-purification effect in CdTe:Gd crystals Nikonyuk, E.S. Shlyakhovyi, V.L. Kovalets, M.O. Kuchma, M.I. Zakharuk, Z.I. Savchuk, A.I. Yuriychuk, I.M. The temperature dependences (T = 80 – 420 K) of the concentration of charge carriers and the Hall mobility in undoped CdTe and CdTe:Gd single crystals grown by the Bridgman method are studied. It is found that the conductivity type of CdTe:Gd crystals changes with increase in the impurity concentration in the melt: n-conductivity at 5.10¹⁷ – 3.10¹⁸ cm⁻³ and p-conductivity at 3.10¹⁸ – 10¹⁹ cm⁻³. The concentrations and ionization energies of A₁ (EA₁ = 0.05 eV) and A₂ (EA₂ = 0.12-0.15 eV) acceptors are determined from the temperature dependences of the Hall coefficient and the mobility of carriers. A long-term thermal treatment of gadolinium-doped p-CdTe crystals in the range 663 – 713 K is accompanied by the “self-purification” of the material from A₂- acceptors and compensating donors. The Gd impurity at C₀ > 3.10¹⁸ cm⁻³ is shown to bring no new electrical active centers into the CdTe lattice, by reducing, at the same time, the background of residual impurities. It is suggested that Te precipitates and Te inclusions serve as sinks for the above defects. 2008 Article Self-purification effect in CdTe:Gd crystals / E.S. Nikonyuk, V.L.Shlyakhovyi, M.O. Kovalets, M.I. Kuchma, Z.I. Zakharuk, A.I. Savchuk, I.M. Yuriychuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2008. — Т. 11, № 1. — С. 40-42. — Бібліогр.: 7 назв. — англ. 1560-8034 PACS 61.72.Vv, 71.55.-i http://dspace.nbuv.gov.ua/handle/123456789/118666 en Semiconductor Physics Quantum Electronics & Optoelectronics Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description The temperature dependences (T = 80 – 420 K) of the concentration of charge carriers and the Hall mobility in undoped CdTe and CdTe:Gd single crystals grown by the Bridgman method are studied. It is found that the conductivity type of CdTe:Gd crystals changes with increase in the impurity concentration in the melt: n-conductivity at 5.10¹⁷ – 3.10¹⁸ cm⁻³ and p-conductivity at 3.10¹⁸ – 10¹⁹ cm⁻³. The concentrations and ionization energies of A₁ (EA₁ = 0.05 eV) and A₂ (EA₂ = 0.12-0.15 eV) acceptors are determined from the temperature dependences of the Hall coefficient and the mobility of carriers. A long-term thermal treatment of gadolinium-doped p-CdTe crystals in the range 663 – 713 K is accompanied by the “self-purification” of the material from A₂- acceptors and compensating donors. The Gd impurity at C₀ > 3.10¹⁸ cm⁻³ is shown to bring no new electrical active centers into the CdTe lattice, by reducing, at the same time, the background of residual impurities. It is suggested that Te precipitates and Te inclusions serve as sinks for the above defects.
format Article
author Nikonyuk, E.S.
Shlyakhovyi, V.L.
Kovalets, M.O.
Kuchma, M.I.
Zakharuk, Z.I.
Savchuk, A.I.
Yuriychuk, I.M.
spellingShingle Nikonyuk, E.S.
Shlyakhovyi, V.L.
Kovalets, M.O.
Kuchma, M.I.
Zakharuk, Z.I.
Savchuk, A.I.
Yuriychuk, I.M.
Self-purification effect in CdTe:Gd crystals
Semiconductor Physics Quantum Electronics & Optoelectronics
author_facet Nikonyuk, E.S.
Shlyakhovyi, V.L.
Kovalets, M.O.
Kuchma, M.I.
Zakharuk, Z.I.
Savchuk, A.I.
Yuriychuk, I.M.
author_sort Nikonyuk, E.S.
title Self-purification effect in CdTe:Gd crystals
title_short Self-purification effect in CdTe:Gd crystals
title_full Self-purification effect in CdTe:Gd crystals
title_fullStr Self-purification effect in CdTe:Gd crystals
title_full_unstemmed Self-purification effect in CdTe:Gd crystals
title_sort self-purification effect in cdte:gd crystals
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
publishDate 2008
url http://dspace.nbuv.gov.ua/handle/123456789/118666
citation_txt Self-purification effect in CdTe:Gd crystals / E.S. Nikonyuk, V.L.Shlyakhovyi, M.O. Kovalets, M.I. Kuchma, Z.I. Zakharuk, A.I. Savchuk, I.M. Yuriychuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2008. — Т. 11, № 1. — С. 40-42. — Бібліогр.: 7 назв. — англ.
series Semiconductor Physics Quantum Electronics & Optoelectronics
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first_indexed 2023-10-18T20:32:49Z
last_indexed 2023-10-18T20:32:49Z
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