Diffusion Processes in Ti–Si Systems during Silicide Formation

Two methods of creation of the TiSi₂(C54) stable phase are reviewed, and their comparison is considered. The formation of the structure of TiSi₂(C54) nanosize films on monocrystalline Si is studied. As shown, the TiSi₂(C54) formation is carried out faster (≅ 55 s) by low-energy thermion deposition (...

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Bibliographic Details
Date:2013
Main Authors: Bogdanov, S.E., Beddies, G., Daniel, M., Makogon, Yu.N.
Format: Article
Language:English
Published: Інститут металофізики ім. Г.В. Курдюмова НАН України 2013
Series:Наносистеми, наноматеріали, нанотехнології
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/75923
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Diffusion Processes in Ti–Si Systems during Silicide Formation / S. E. Bogdanov, G. Beddies, M.Daniel, Yu.N. Makogon // Наносистеми, наноматеріали, нанотехнології: Зб. наук. пр. — К.: РВВ ІМФ, 2013. — Т. 11, № 2. — С. 295-302. — Бібліогр.: 7 назв. — анг.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:Two methods of creation of the TiSi₂(C54) stable phase are reviewed, and their comparison is considered. The formation of the structure of TiSi₂(C54) nanosize films on monocrystalline Si is studied. As shown, the TiSi₂(C54) formation is carried out faster (≅ 55 s) by low-energy thermion deposition (LETD) of Ti on mono-Si than by magnetron sputtering with post-annealing of 150 s and more. As noted, the electrical-resistivity value for TiSi₂(C54) nanosize film deposited by LETD is equal to ρv = 13.5 μΩ∙cm, and with magnetron sputtering, it is equal to ρv = 24 μΩ∙cm. A phenomenological model for titanium disilicide formation on mono-Si by low-energy thermion deposition of titanium is proposed.