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Influence of isochronal annealing in the range of 350–1100 oC on the structural properties and the intrinsic absorption edge in thin silicon films doped with tin (a-SiSn) has been studied. It is found that as-deposited a-SiSn films with a tin content of about 4 at.%, unlike undoped a-Si ones, contai...

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Bibliographic Details
Date:2018
Main Authors: Rudenko, R. M., Voitovych, V. V., Kras’ko, M. M., Kolosyuk, A. G., Kraichynskyi, A. M., Yukhymchuk, V. O., Makara, V. A.
Format: Article
Language:English
Ukrainian
Published: Publishing house "Academperiodika" 2018
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Online Access:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2018349
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Journal Title:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Summary:Influence of isochronal annealing in the range of 350–1100 oC on the structural properties and the intrinsic absorption edge in thin silicon films doped with tin (a-SiSn) has been studied. It is found that as-deposited a-SiSn films with a tin content of about 4 at.%, unlike undoped a-Si ones, contain silicon nanocrystals with a crystallite size of about 4 nm and a crystalline fraction of about 65%. It is shown that, in the course of isochronal annealing of a-SiSn specimens in the interval of 350–1100 oC, the size of silicon nanocrystals in the amorphous matrix gradually increases to about 7 nm, and the fraction of crystalline phase to about 100%. Crystallization in undoped a-Si is observed only after the annealing at temperatures above 700 oC. The influence of tin on the optical band gap in a-Si as a function of the isochronal annealing temperature is analyzed.